Ferrocenyl Thiolates as Ligands in the Enantioselective Copper-Catalyzed Substitution of Allylic Acetates with Grignard Reagents
- 31 December 2001
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 2001 (Special ) , 0923-0926
- https://doi.org/10.1055/s-2001-14667
Abstract
The application of ferrocenyl thiolates as ligands in copper-catalyzed asymmetric substitution reactions of allylic acetates with Grignard reagents is reported. The catalyst from lithium thiolate 12 gave the γ-products in high selectivity and with up to 64% ee.Keywords
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