Self-Assembly of Interlocked Supramolecular Dendrimers
- 3 March 2004
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 69 (7) , 2618-2621
- https://doi.org/10.1021/jo035798u
Abstract
Interlocked supramolecular dendrimers were spontaneously self-assembled from molecular components, metallocycles, and dumbbells bearing benzyl ether repeating units. Here, the metallocycles were in situ self-assembled from L-shaped ligands with dendritic branches, 2,3-dimethyl-2-butene and osmium tetraoxide. The supramolecular dendrimers were stabilized by hydrogen-bonding interactions between the pyridine-2,6-dicarboxamide unit in the metallocycle and the adipamide unit in the dumbbell.Keywords
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