Relative rate constants for the reaction of ground-state oxygen atoms with fluorinated ethylenes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 67, 3503-3512
- https://doi.org/10.1039/tf9716703503
Abstract
Relative rate constants for the reaction of oxygen atoms with the fluorinated ethylenes in the gas phase have been measured at 23°C with the following results (relative to ethylene): CH2 CHF–0.38; CH2 CF2–0.22; cis-CHFCHF–0.32; trans-CHFCHF–0.54;CHFCF2–0.57; CF2 CF2–1.60. The results are compared with data for other atoms and radicals with the same olefins, and briefly discussed in terms of the electronic changes produced in the double bond by fluorine substitution.Keywords
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