A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3? trianion

Abstract
The anion [RH11(CO)23]3–, obtained through oxidation of [RH7(CO)16]3– or various redox considerations, contains a metal polyhedron of ideal D3h symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.

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