Electrochemical conversion of functionalised aryl chlorides and bromides to arylzinc species
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 283-284
- https://doi.org/10.1039/c39920000283
Abstract
Electroreduction of aromatic chlorides or bromides in a cell fitted with a sacrificial zinc anode, in the presence of a nickel, 2,2′-bipyridine complex affords the corresponding organozinc species in good yield.Keywords
This publication has 4 references indexed in Scilit:
- A facile synthesis of aryl trifluoromethyl ketonesTetrahedron Letters, 1991
- Metal exchange between an electrogenerated organonickel species and zinc halide: application to an electrochemical, nickel-catalyzed Reformatsky reactionThe Journal of Organic Chemistry, 1991
- The direct formation of functionalized alkyl(aryl)zinc halides by oxidative addition of highly reactive zinc with organic halides and their reactions with acid chlorides, .alpha.,.beta.-unsaturated ketones, and allylic, aryl, and vinyl halidesThe Journal of Organic Chemistry, 1991
- A new preparation of highly functionaized aromatic and heteroaromatic zinc and copper organometallicsTetrahedron Letters, 1990