Samarium(II) iodide promoted ring contraction of carbohydrate derivatives: an expeditious synthesis of functionalised cyclopentanes
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1373-1374
- https://doi.org/10.1039/c39950001373
Abstract
Aldehydo methyl pyranosides undergo ring contraction induced by treatment with samarium(II) iodide, in the presence of HMPA and tert-butyl alcohol, to give highly functionalised cyclopentanes.Keywords
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