Mononuclear heterocyclic rearrangements. Part 7. Evidence for general base catalysis in the rearrangement of the Z-phenylhydrazone of 3-benzoyl-5-phenyl-1,2,4-oxadiazole into 2,5-diphenyl-4-benzoylamino-1,2,3-triazole in dioxan–water
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 10,p. 1325-1328
- https://doi.org/10.1039/p29810001325
Abstract
The title reaction has been studied at various pS+ and buffer concentrations. Kinetic constants for uncatalysed and catalysed pathways have been calculated. A mechanism for the rearrangement is offered.Keywords
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