Coupling electrocatalysis (electron transfer chain) with organometallic catalysis: polymerisation of terminal alkynes catalysed by [W(CO)3(NCMe)3] and [Fe(cp)2]+PF6–(cp =η5-cyclopentadienyl)
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 472-473
- https://doi.org/10.1039/c39880000472
Abstract
Terminal alkynes (RC2H; R = Ph, Bun) are instantaneously polymerized at 20 °C by 1% of W(CO)3(NCMe)3(1) and 0.01% of [Fe(cp)2]+PF6 –(2) in a system which couples electrocatalysis (electron transfer chain) with organometallic catalysis (cp =η5-cyclopentadienyl).Keywords
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