Synthesis and ligand substitution reactions of a homoleptic acetonitrile dipalladium(i) complex

Abstract
The first homoleptic nitrile dipalladium(I) complex [Pd2(CH3CN)6][BF4]2 is prepared; the CH3CN ligand undergoes facile displacement by phosphine or bidentate nitrogen ligands while the Pd–Pd bond remains intact.

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