X-Ray crystal structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2](BF4)2and the selective stabilisation of the nickel(I) oxidation state by a quinquedentate macrocyclic ligand
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 546-547
- https://doi.org/10.1039/c39820000546
Abstract
The single crystal X-ray structure of the pentagonal bipyramidal nickel(II) complex [NiII(L)(H2O)2](BF4)2 involving the quinquedentate macrocyclic ligand L is reported; electrochemical reduction of a series of related nickel(II) complexes [NiII(L)X2](BF4)2 yields in solution d9 nickel(I) species.Keywords
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