Investigation of photolysis of o-nitrophenols by electron spin resonance spectroscopy. Characterisation of 1,2-benzoquinone monohydroxyimine free radicals
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 13,p. 1380-1384
- https://doi.org/10.1039/p29750001380
Abstract
The photolysis of tetrahydrofuran (THF) solutions containing o-nitrophenols and di-t-butyl peroxide (DTBP) has been examined by e.s.r. spectroscopy. In carefully degassed solutions a series of 1,2-benzoquinone monohydroxyimine free radicals are formed, the structures of which have been confirmed using an unambiguous synthesis by oxidation of appropriate nitrosophenols in a flow system. The origin of hyperfine splittings is such radicals has been evaluated. Structures are tentatively proposed for free radicals observed during the photolysis of inefficiently degassed THF solutions of o-nitrophenols and DTBP; the same radicals are obtained when analogous nitrosophenols are photolysed under identical conditions.Keywords
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