The radiolysis of ethanol. VI. Hydrogen precursors at −196°C
Open Access
- 15 March 1967
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 45 (6) , 635-640
- https://doi.org/10.1139/v67-104
Abstract
Reactions of trapped (or solvated) electrons in solid ethanol have been studied. The following reactions occur at − 196 °C. [Formula: see text] [Formula: see text] [Formula: see text]The activation energy of reaction [6] is roughly 5 kcal/mole. Reaction [7] occurs with electrons that have not yet been trapped by the medium.Hydrogen atoms appear to be able to abstract from ethanol and to add to propylene at − 196 °C.Keywords
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