Synthesis of novel labile rotenoids with unnatural trans-B/C ring systems
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 1,p. 204-205
- https://doi.org/10.1039/p19890000204
Abstract
6a,12a-Dehydrorotenoids are cleanly reduced in 1,4-fashion by DIBAL to give rotenoids having the unstable, unnatural, trans-B/C fusion, readily epimerised by acid to the cis-forms: an X-ray structure for (±)-trans-isorotenone confirms the nature of the ring fusion.This publication has 0 references indexed in Scilit: