Alkyl and alkylidene derivatives of titanium supported by carbazole ligation
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1109-1110
- https://doi.org/10.1039/a701493g
Abstract
The bis(benzyl) [(cb) 2 Ti(CH 2 Ph) 2 ] 1 and alkylidene bridged dimer [(cb) 2 Ti(µ-CHSiMe 3 ) 2 Ti(cb) 2 ] 3 are formed by adding carbazole (Hcb) to the tetraalkyls [TiR 4 ] (R = CH 2 Ph, CH 2 SiMe 3 ); the reaction of 1 and 3 with 2,6-dimethylphenyl isocyanide leads to organometallic products containing new carbon–carbon bonds.Keywords
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