Cationic Complexes of Platinum(l1) Containing Olefins: A Type of Highly Electrophilic Substrate
- 1 April 1994
- journal article
- research article
- Published by Taylor & Francis in Comments on Inorganic Chemistry
- Vol. 16 (1-2) , 95-112
- https://doi.org/10.1080/02603599408035853
Abstract
The topic discussed in this article is the synthesis of cationic complexes of plati-num(I1) containing η2−olefins, their reaction with nucleophiles, and the cleavage, under acidic conditions, of the platinum-carbon bond of the addition productsobtained therefrom. Some general features related to the electrotl distribution and bonding, the structural and conformational preferences, the reaction mechanisms and reactivity are discussed.Keywords
This publication has 22 references indexed in Scilit:
- Rapid inversion versus stable chiral center formation. Different behavior of coordinated nitrogens in four- and five-coordinate platinum(II) complexes with N,N'-disubstituted ethylenediaminesInorganic Chemistry, 1988
- Chelate ring size and effect of N-substituents as limiting factors for the formation of cationic chloro-diamine-η2-ethene-platinum(II) complexesInorganica Chimica Acta, 1984
- Single-crystal polarized electronic absorption spectrum and ligand-field interpretation of the bonding of Zeise's saltJournal of the American Chemical Society, 1984
- Stable η- and σ-ethene cationic complexes of platinum(II)Inorganica Chimica Acta, 1980
- Relationship between olefinic .pi. complexes and three-membered ringsJournal of the American Chemical Society, 1979
- Decomposition of [Pt(C2H4)Cl2(bipyridyl)] to [PtCl2(bipyridyl)] and ethylene in different solventsInorganica Chimica Acta, 1976
- Cationic acetylenic platinum(II) compounds and their derivatives. V. Comparative study with .pi.-olefinic complexesInorganic Chemistry, 1973
- Olefin and acetylene complexes of platinum and palladiumChemical Reviews, 1969
- The vibrational spectra of several platinum-ethylene complexes: K[PtCl3(C2H4)]·H2O (Zeise's salt), K[PtCl3(C2D4)] · H2O and [PtCl2(C2H4)]2Spectrochimica Acta Part A: Molecular Spectroscopy, 1969
- Geometries and charge distributions of organic ligands. I. Metal-carbon .pi. bonding and the geometry of acetyleneJournal of the American Chemical Society, 1968