Synthesis of Mono- and Ditungstaboranes from Reaction of Cp*WCl₄and [Cp*WCl₂]₂with BH₃·thf or LiBH₄(Cp* = η⁵-C₅Me₅). Control of Reaction Pathway by Choice of Monoboron Reagent and Oxidation State of Metal Center

This publication has 47 references indexed in Scilit:

• Cluster Expansion Reactions of Group 6 Metallaboranes. Syntheses, Crystal Structures, and Spectroscopic Characterizations of (Cp*Cr)₂B₅H₉, (Cp*Cr)₂B₄H₈Fe(CO)₃, (Cp*Cr)₂B₄H₇Co(CO)₃, and (Cp*Mo)₂B₅H₉Fe(CO)₃
  Inorganic Chemistry, 1998
• Isolation of a Nonicosahedral Intermediate in the Isomerization of an Icosahedral Metallacarborane
  Angewandte Chemie International Edition in English, 1997
• Synthesis of η-cyclopentadienyl-polyborane derivatives of molybdenum and tungsten
  J. Chem. Soc., Dalton Trans., 1995
• Synthesis of Cobaltaborane Clusters from [Cp*CoCl]2 and Monoboranes. New Structures and Mechanistic Implications
  Organometallics, 1994
• Alkylidyne(carbaborane) complex of the group 6 metals. 3. Facile transformations of 12- and 13-vertex tungstacarborane polyhedra reversible. Framework rearrangement and acid-induced ejection of a cage vertex
  Journal of the American Chemical Society, 1992
• Syntheses and structures of [M(CO)5{B2H4.cntdot.2P(CH3)3}] and [M(CO)4{B2H4.cntdot.2P(CH3)3}] (M = chromium, molybdenum, tungsten)
  Inorganic Chemistry, 1992
• Synthesis of the WW triply bonded dimers [W₂(η-C₅H₄R)₂X₄](X = Cl, R = Me or Prⁱ; X = Br, R = Prⁱ) and X-ray crystal structures of [W(η-C₅H₄Prⁱ)Cl₄] and [W₂(η-C₅H₄Prⁱ)₂Cl₄]
  J. Chem. Soc., Dalton Trans., 1990
• Bent-sandwich derivatives of tantalum bearing one or two pentamethylcyclopentadienyl ligands
  Organometallics, 1986
• (Pentamethylcyclopentadienyl)iridium polyhydride complexes: synthesis of intermediates in the mechanism of formation of (pentamethylcyclopentadienyl)iridium tetrahydride and the preparation of several iridium(V) compounds
  Journal of the American Chemical Society, 1985
• Crystal and molecular structure of 2-(η-cyclopentadienyl)-2-cobalta-nido-pentaborane(9)
  Journal of the Chemical Society, Chemical Communications, 1976