Chlorofluorination reactions of sulphur(IV) fluorides

1 January 1969

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 15,p. 864b-865
https://doi.org/10.1039/c2969000864b

Abstract

Trifluoromethylsulphur chloride tetrafluoride, CF₃SF₄CI, results from the action of chlorine on CF₃SF₃ in the presence of caesium fluoride, and CH₃N:SF₂ reacts with chlorine to give CH₂CIN:SF₂, CHCI₂N:SF₂, and CF₃N:SCl₂.

Keywords

SULPHUR
CHLOROFLUORINATION
FLUORIDES
CHLORIDE
REACTS
CHCI2N
CF3N
CAESIUM
GIVE