Diels–Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 542-544
- https://doi.org/10.1039/c39790000542
Abstract
The addition of fumaryl chloride to furan, followed by hydrolysis and bromolactonisation of the adduct, leads to the bromo-lactone acid (2a) which serves as a precursor for the synthesis of the reduction products (5a), (5b), and (6a) of cis-maneonene-A and of the tosylate (6b) whose X-ray crystal structure has been determined.Keywords
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