Synthesis and structural characterisation of two novel GdIIIβ-diketonates [Gd4(µ3-OH)4(µ2-H2O)2(H2O)4(hfpd)8]·2C6H6·H2O 1 and [Gd(hfpd)3(Me2CO)(H2O)] 2(hfpd–H = 1,1,1,5,5,5-hexafluoropentane-2,4-dione)
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 2455-2456
- https://doi.org/10.1039/c39940002455
Abstract
Two novel GdIII–hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M4O6 bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with the metal having square antiprismatic geometry.Keywords
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