C2-Symmetric N-(.BETA.-Mercaptoethyl)pyrrolidine as a Chiral Catalyst Ligand in the Addition Reaction of Aldehydes and Diethylzinc.
- 1 January 1996
- journal article
- Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN
- Vol. 44 (2) , 454-456
- https://doi.org/10.1248/cpb.44.454
Abstract
A chiral C2-symmetric N-(β-mercaptoethyl)pyrrolidine bearing 6-membered benzylidene acetal functionalities fused at the 2, 3- and 4, 5-positions was found to exhibit high efficiency in the asymmetric addition reaction of aldehydes with diethylzinc.Keywords
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