Syntheses of 3-Deoxy-3-Fluoroglucosamine Derivatives
- 1 January 1990
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 9 (4) , 359-368
- https://doi.org/10.1080/07328309008543839
Abstract
Methyl 2-acetamido-4,6-di-0-acetyl-2,3-dideoxy-3-fluoro-α-D-glucopyranoside (5) and methyl 2-diallylamino-2,3,6-trideoxy-3,6-difluoro-4-0-methanesulfonyl-α-D-glucopyranoside (10) were prepared from methyl 4,6-0-benzylidene-α-D-glucopyranoside. Fluorination at C-3 was carried out by ring opening of an aziridinium ion. Two fluorinating reagents were used depending on the starting material.This publication has 9 references indexed in Scilit:
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