Alumina as a Desilicohalogenating Agent in the Stereoselective Synthesis of Vinyl Halides
- 1 January 1977
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 7 (7) , 475-482
- https://doi.org/10.1080/00397917708050783
Abstract
Recently we reported a stereoselective synthesis of vinyl halides using vinylsilanes as precursors (see Scheme I).1 In the desilicohalogenation step an oxygen base (NaOMe) was used, necessitating a strongly basic media in a polar solvent.Keywords
This publication has 3 references indexed in Scilit:
- The stereospecific synthesis of vinyl halides using a vinylsilane as the synthetic precursorTetrahedron Letters, 1974
- Chemistry of bent bonds. XLIII. Cycloadditions to cyclic 1,3-dienes. Diels-Alder route to inside-outside bicyclicsJournal of the American Chemical Society, 1974
- The Stereochemistry of the Addition of Silicochloroform to Acetylenes. A Comparison of Catalyst SystemsJournal of the American Chemical Society, 1961