A rapid porphyrin metallation
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 192-194
- https://doi.org/10.1039/c39810000192
Abstract
In aqueous dimethylformamide solution meso-αααα-tetra(o-maleamoylphenyl)porphyrin undergoes rapid metal incorporation (CuII, ZnII, CoII, and NiII) by a mechanism featuring rate-determining intramolecular transfer of the metal ion from the carboxylate binding site to the porphyrin nucleus.Keywords
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