An ambident carbanion stabilized by bivalent sulphur
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 913-914
- https://doi.org/10.1039/c29700000913
Abstract
2-α-Styryl-1,3-dithian reacts with strong bases to yield an ambident carbanion: the importance of sulphur 3d-orbital conjugation in the stabilization of such ambident carbanions is assessed with CNDO calculations.Keywords
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