Reactions of hydrazines with platinum–nitrile complexes; X-ray structural characterization and electrochemistry of trans-bis-1-acetyl-3-t-butyl-1,2,4-triaza-butadieneplatinum
- 1 January 1973
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 297-299
- https://doi.org/10.1039/c39730000297
Abstract
Mono- and bi-dentate platinum complexes of ligands derived from R1NNCR2 NR3 are described: X-ray crystal structure analysis and E.S.C.A. data indicate that the intensely green [Pt{HNC(But)N2Ac}2] has extensive delocalization of electrons within the chelate ring; the complex undergoes a reversible one-electron reduction to a paramagnetic species.Keywords
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