Abstract
The results of polarized neutron diffraction measurements on ferromagnetic BCC Fe-V alloys are analysed within the multiband CPA theory. A Hubbard Hamiltonian with intra- and interatomic exchange interaction is used. Both Hubbard and exchange terms are treated in the Hartree-Fock approximation. A good agreement for the magnetic moment and asphericity of its distribution is found. It is shown that the increase of the asphericity parameter with vanadium content is caused by the transfer of eg electrons from vanadium to iron sites. This transfer is responsible also for the occurrence of a negative moment on vanadium confirmed in diffuse scattering measurements.