The reactivity of organophosphorus compounds. Part XXIV. Acidic hydrolysis of dialkyl methylphosphonates
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 144-146
- https://doi.org/10.1039/j29690000144
Abstract
Rates of acidic hydrolysis of dialkyl methylphosphonates [(RO)2P(O)Me and (RO)(EtO)P(O)Me, where R is primary, secondary (mainly), and tertiary] at 100° in 50% aqueous dioxan, containing benzenesulphonic acid (1 N), have been measured and the relative rates of hydrolysis are compared with the previously reported relative rates of ageing of phosphonylated cholinesterases.Keywords
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