Spontaneous formation of reactive oxometal porphyrins by oxygen atom transfer from dioxirane
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1782-1784
- https://doi.org/10.1039/c39900001782
Abstract
Oxygen atom transfer to manganese(II) tetraphenylporphyrin (tpp) and iron(II) tetramesitylporphyrin (tmp) is readily effected at < –10 °C with dimethyldioxirane in anhydrous acetone to afford the labile oxometal species OMnIV(tpp) and OFeIV(tmp) in quantitative yields.Keywords
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