The preparation and photolysis of 3-aryl-3H-diazirines
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 7,p. 686-694
- https://doi.org/10.1039/p29750000686
Abstract
The preparation of a number of 3-aryl-3H-diazirines is reported. On irradiation, these materials undergo both photolytic fragmentation to the arylcarbene and photoisomerisation to the linear diazo-compound which is then itself photolysed. The existence of a second intermediate is also apparent from the spectral changes observed.Keywords
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