Concerning the absolute configuration of proton exchange at a prochiral centre in sulphoxides
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 23,p. 1415-1416
- https://doi.org/10.1039/c29690001415
Abstract
Deuterium exchange of the kinetically more labile proton in (S)-benzyl methyl sulphoxide yields the (R) configuration at the benzylic carbon atom, an observation opposite to what others have previously reported.Keywords
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