Transient Laser Frequency Modulation Spectroscopy
- 1 October 2000
- journal article
- Published by Annual Reviews in Annual Review of Physical Chemistry
- Vol. 51 (1) , 243-274
- https://doi.org/10.1146/annurev.physchem.51.1.243
Abstract
Explicitly time-dependent implementations of optical frequency modulation spectroscopy have been recently applied to a wide range of problems in chemical physics. We provide a brief description of the methodology, with an emphasis on its intrinsic advantages for interrogating transient species. Several examples highlight the application of the technique to high-resolution absorption spectra of free radicals, rate measurements for gas-phase reactions, and Doppler spectroscopy of the gas-phase products of photoinitiated reactions.Keywords
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