Use of2H–13C n.m.r. coupling patterns in terpenoid biosynthesis
- 1 January 1981
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 649-650
- https://doi.org/10.1039/c39810000649
Abstract
The heteronuclear 2H-13C n.m.r. coupling pattern of methyl botryaloate, a relative of dihydro-botrydial, derived from [4-2H2, 4-13C]mevalonic acid, has been used distinguish between two possible pathways for a biosynthetic rearrangement; a 1:3 hydrogen shift occurs.Keywords
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