The reaction of organic dihalides with organyltelluride (RTe–) anions : telluronium salts and charge-transfer complexes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 10,p. 2143-2146
- https://doi.org/10.1039/dt9830002143
Abstract
The reaction of NaTeR (R =p-EtOC6H4 or Ph) with organic dihalides (CH2)nX2(n= 1–4) affords telluronium salts (n= 3 or 4; X =Cl or Br) the nature of which is discussed. For n= 1 (X = Br or I) the products are formulated as charge-transfer complexes of stoicheiometry (RTe)2CH2·CH2X2. For n= 2, elimination of ditelluride occurs with formation of an alkene. The compound NaTeR is shown to be an effective dehalogenating agent for vic-dihalides. Some 125Te Mössbauer data are discussed and it is suggested that the unusually low value of Δ(7.58 mm s–1) for (p-EtOC6H4Te)2CH2·CH2Br2 relates to removal of 5p-electron density from the spare-pair orbital via the charge-transfer interaction. The related di-iodomethane complex gives a solid-state e.s.r. signal. Mass spectroscopic data are discussed and these support the formulations proposed.Keywords
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