Reactions of phosphinothioylidene (R–PS) as intermediate
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1186-1187
- https://doi.org/10.1039/c29710001186
Abstract
Dechlorination of phenylphosphonothioic di-chloride with magnesium in the presence of 2,3-dimethylbutadiene, benzil, and diethyl disulphide gave 1,2-thiaphosphorin, 1,3,2-dioxaphospholene, and phosphonotrithioate derivatives, respectively, and the formation of these products was explained in terms of the intermediacy of phenylphosphinothioylidene (PhPS).Keywords
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