Chirality in transition-metal chemistry. The formation of diastereomers in the reaction of the stereoisomers of hexa-2,4-diene with palladium chloride
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 13,p. 799-800
- https://doi.org/10.1039/c29700000799
Abstract
Diastereomeric pairs of enantiomers of 1-(1-chloroethyl)- 3-methyl-π-allylpalladium chloride are formed when either trans,trans-, cis,cis-, or ci,strans-hexa-2,4-diene are allowed to react with palladium chloride at –40° in an aprotic solvent: these reactions can be employed to effect the conversions, cis,cis→trans,transcis, trans-hexa-2,4-diene.Keywords
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