A new approach to the study of solid-state reactions
- 1 January 1986
- journal article
- research article
- Published by Taylor & Francis in Philosophical Magazine A
- Vol. 53 (1) , L1-L6
- https://doi.org/10.1080/01418618608242801
Abstract
A new technique for the study of solid-state reactions is described. The new approach uses a thin-film specimen geometry and is ideal for transmission-electron-microscopy studies of the same specimen before and after the Occurrence of solid-state reactions. The technique of illustrated by an investigation of the growth of Ni-Al spinel on, and into, an alumina substrate. Near-topotactic relationships and exact topotactic alignment of the spinel and the alumina were both found. The {111} plane of the spinel is parallel either to the (00011) plane of the alumina or to the {1120} plane of the alumina. Further heat treatment of such samples directly reveals the mechanism by which the spinel particles grow.Keywords
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