The trans-influence of the ligand trimethylsilylmethylide (Me3SiCH2–) in platinum(II) complexes and the crystal structure of a platinum(II) alkyl
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 613-614
- https://doi.org/10.1039/c39720000613
Abstract
Spectroscopic and crystallographic data are presented for trans-[PtCl(CH2SiMe3)(PMe2Ph)2]; by comparison of data for cis-[Pt(CH2Y)2(PMe2Ph)2] and trans-[PtCl(CH2Y)(PMe2Ph)2](Y = H, Ph, or Me3Si) it is concluded that the trans-influence of the ligands decreases in the order Ph2MeSi– > YCH2 –, and that the group Y has a minor role.Keywords
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