Highly Efficient Palladium Catalyst System for Insertion of Acetylenes into Si–Si Bonds. A New Method for Modification of Silicon-containing Polymers
- 1 February 1991
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 20 (2) , 241-244
- https://doi.org/10.1246/cl.1991.241
Abstract
The Pd(dba)2–2P(OCH2)3CEt (dba = dibenzylideneacetone) system exhibited highly efficient catalysis in the insertion of acetylenes into Si–Si bonds of hexamethyldisilane, octamethyltrisilane, poly[(disilanylene)phenylene] , poly[(disilanylene)ethylene], and poly(dimethylsilylene).Keywords
This publication has 5 references indexed in Scilit:
- Platinum complex catalyzed double silylation of ethylene and norbornene with disilanesOrganometallics, 1990
- Polysilane high polymersChemical Reviews, 1989
- Photolysis of polymeric organosilicon systems. 4. Photochemical behavior of poly[p-(disilanylene)phenylene]Organometallics, 1987
- The polysilane high polymersJournal of Organometallic Chemistry, 1986
- Reaction of disilanes with acetylenes : I. Stereoselective addition of methoxymethyldisilanes to phenylacetylene catalyzed by group-VIII metal phosphine complexesJournal of Organometallic Chemistry, 1980