Hydride to carbene migration at molybdenum; the isomerisation of Mo(H){C[CH2]3NMe}(CO)2(η-C5H5) to Mo(CO)2{η2-CH[CH2]3NMe}(η-C5H5)
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1185-1186
- https://doi.org/10.1039/c39860001185
Abstract
Treatment of the anion [Mo{[graphic omitted]Me}(CO)2(η-C5H5)]– with acid leads to the hydrido molybdenum carbene Mo(H){[graphic omitted]Me}(CO)2(η-C5H5) which isomerises by a hydride to carbene migration process resulting in M[graphic omitted]Me}(η-C5H5).Keywords
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