The reaction of halogens with [(π-C5H5)Fe(CO)2]2and related compounds

Abstract
The reaction of [(π-C5H5)Fe(CO)2]2 with iodine in chloroform solution has been shown to proceed via a rapidly formed ionic intermediate {[(π-C5H5)Fe(CO)2]2I} X (X= I3 or I) which slowly decomposes to the final product, (π-C5H5)Fe(CO)2I.

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