The first enantioselective total synthesis of (+)-laurene
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1695-1697
- https://doi.org/10.1039/c39920001695
Abstract
The cyclopentenone 8, synthesised by palladium mediated ring expansion of the chiral vinylcyclobutanols 3 and 4, is converted to the thermodynamically unstable ketone 16 which on methylenation gives (+)-laurene 1.Keywords
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