Enantioselective addition of diethylzinc to α-branched aldehydes
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 2009-2010
- https://doi.org/10.1039/c39940002009
Abstract
Reaction of diethylzinc with α-branched aldehydes in the presence of a catalytic amount of (1R,2S)-(–)-1-phenyl-2-piperidinopropane-1-thiol 1 provided the corresponding secondary alcohols in almost 100% enantiomeric excess.Keywords
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