The structural chemistry of organotin derivatives of 5-mercapto-3-phenyl-1,3,4-thiadiazoline-2-thione: supramolecular structures involving intermolecular Sn⋯S, N–H⋯S or S⋯S interactions
- 19 February 2002
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 6,p. 1036-1045
- https://doi.org/10.1039/b109726a
Abstract
Seven new organotin complexes of 5-mercapto-3-phenyl-1,3,4-thiadiazoline-2-thione (I), RnSn(PhN2C2S3)4 − n [n = 1, R = Bu (1); n = 2, R = Ph (2), Bu (3), Me (4) and n = 3, R = Ph (5), Bu (6), Me (7)], along with the 4,4′-bipy and 4-PyNH2 adducts of 7, [Me3Sn(PhN2C2S3)]2·(4,4′-bipy) (8) and [Me3Sn(4-PyNH2)2]+[PhN2C2S3]− (9), respectively, have been synthesised. The coordination behaviour of I in 1–8 ranges from S(1) monodentate to S(1) + S(3) bidentate bridging, while the crystal structure of 9 contains the ligand as a non-bonded anion. The supramolecular structures of 2, 7 and 8 have been found to consist of 1-D molecular chains built up by Sn⋯S (7) or S⋯S (2, 8) intermolecular linkages. Additionally, the 1-D polymers of 7 aggregate in ‘ribbon’-type double chains through S⋯S interactions and further self-organise via Ph⋯Ph face-to-face π-stacking, leading to a 3-D network. Extended intermolecular N–H⋯S interactions in the crystal lattice of 9 link the molecules in a 3-D network.Keywords
This publication has 36 references indexed in Scilit:
- Synthesis and spectral characterisation of organotin(IV) 1,3,5-triazine-2,4,6-trithiolato complexes, including the crystal structures of 1,3,5-(R3Sn)3C3N3S3 (R=Me, Ph)Journal of Organometallic Chemistry, 2001
- The first single source deposition of tin sulfide coatings on glass: aerosol-assisted chemical vapour deposition using [Sn(SCH2CH2S)2]Journal of Materials Chemistry, 2001
- Deposition of tin sulfide thin films from tin(iv) thiolate precursorsJournal of Materials Chemistry, 2000
- Deposition of tin sulfide thin films from novel, volatile (fluoroalkythiolato)tin(iv) precursorsJournal of Materials Chemistry, 2000
- Synthesis, characterisation and reaction chemistry of organotin-substituted bis(thiotetrazoles): supramolecular metallotetrazole structures containing hard and soft donorsJ. Chem. Soc., Dalton Trans., 1998
- Crystal and molecular structure of 1-phenyl-1H-tetrazole-5-thiolato-trimethyltin(IV), Me3SnSCN4Ph, exhibiting unusual trimeric associations through intermolecular N → Sn bonds.Journal of Organometallic Chemistry, 1994
- Crystal structure of triphenyl(5-mercapto-1-phenyl-1,2,3,4-tetrazolato)tin(IV)Journal of Organometallic Chemistry, 1994
- New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1∞[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn⋯N bondsPolyhedron, 1994
- Organotin mediated cycloaddition reactions: a re-investigation of the reaction between organotin azides and isothiocyanatesJournal of Organometallic Chemistry, 1992
- Development of the Colle-Salvetti correlation-energy formula into a functional of the electron densityPhysical Review B, 1988