Original syntheses of arylcycloalkanes
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1214-1216
- https://doi.org/10.1039/c39870001214
Abstract
Arylcycloalkanes have been prepared from acetophenone by a three-step sequence involving the synthesis of α-pheny(ω-alkenyl)methylselenides and their reaction with butyl-lithium reagents to give an intermediate which adds across the CC double bond to give 2-methyl-2-phenylcycloalkylmethyl-lithiums with stereocontrol; other syntheses of these compounds are also described.Keywords
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