New mode of bonding of a vinyl ligand to an osmium cluster: the X-ray crystal structure of [HOs3(CO)10(CF3CCHCF3)]

Abstract
The reaction of [H2Os3(CO)10] with CF3CCCF3 in hexane at room temperature leads to the formation of [HOs3(CO)10(CF3CCHCF3)]; a single crystal X-ray analysis reveals that the organic fragment is bonded to all three Os atoms.

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