New, thermodynamically consistent, integral equation for simple fluids
- 1 August 1984
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 30 (2) , 999-1007
- https://doi.org/10.1103/physreva.30.999
Abstract
A new integral equation in which the hypernetted-chain and Percus-Yevick approximations are "mixed" as a function of interparticle separation is described. An adjustable parameter in the mixing function is used to enforce thermodynamic consistency. For simple potential fluids, is constant for all densities, and the solutions of the integral equations are in very good agreement with Monte Carlo calculations. For the one-component plasma, is a slowly varying function of density, but the agreement between calculated solutions and Monte Carlo is also good. This approach has definite advantages over previous thermodynamically consistent equations.
Keywords
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