Solute and solvent effects on chemical equilibria
- 1 September 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 63 (5) , 2064-2073
- https://doi.org/10.1063/1.431544
Abstract
Using a simplified version of a result due to Kirkwood and Buff, a general formalism is developed for the solute and solvent effect on chemical equilibrium. A specific example—an association reaction—is worked out in some detail to detect the nature of the various factors that combine to induce a shift of the equilibrium in one direction or another.Keywords
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