An Improved Method for the Preparation of Acylhydrazines: The First Example of an Enzymatic Hydrazinolysis Reaction

1 January 1990

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1990 (07) , 387-388
https://doi.org/10.1055/s-1990-21099

Abstract

Lipases catalysed the hydrazinolysis reaction of substituted hydrazines in ethyl acetate under mild conditions to give acylhydrazides; the highest yields were obtained with hydrazines substituted with electronegative groups.

Keywords

ACYLHYDRAZINES
ACYLHYDRAZIDES
ELECTRONEGATIVE
GIVE
LIPASES
HIGHEST
ENZYMATIC
CATALYSED
ACETATE
HYDRAZINOLYSIS

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