Naturally occurring linear fused thiazoline-thiazole containing metabolites: total synthesis of (–)-didehydromirabazole A, a cytotoxic alkaloid from blue–green algae
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 14,p. 1629-1636
- https://doi.org/10.1039/p19930001629
Abstract
A concise total synthesis of the thiazoline-thiazole containing metabolite didehydromirabazole A 1 is described. The synthesis uses the unusual amino acid (R)-2-methylcysteine 20 in sequential cyclocondensations with imino ethers as key steps, viz22→32 and 37→38.Keywords
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