Fluorine‐Containing Organozinc Reagents. Part III. A new formylation reaction of fluroalkylzinc halides
- 16 March 1988
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 71 (2) , 369-373
- https://doi.org/10.1002/hlca.19880710210
Abstract
A new Si‐induced Vilsmeier‐type formylation of F‐containing organozinc reagents is described. This two‐step process via the isolable intermediate 10 seems to be quite general for the synthesis of anhydrous polyhalogenated aldehydes.Keywords
This publication has 9 references indexed in Scilit:
- Fluorine-containing organozinc reagents: II. The crystal structure of (1, 1-dichloro-2, 2, 2-trifluoroethylzinc chloride) · 2(dimethylformamide)Journal of Organometallic Chemistry, 1988
- Formylating agentsChemical Reviews, 1987
- Recent advances in the chemistry of halogenofluorocarbonsJournal of Fluorine Chemistry, 1986
- Fluorine‐Containing Organozinc Reagents Part 1 A Simple Synthesis of 2,2‐Dichloro‐3,3,3‐trifluoropropanolHelvetica Chimica Acta, 1986
- Convenient approaches to heterocycles via copper-catalysed additions of organic polyhalides to activated olefinsTetrahedron, 1985
- A mild and convenient procedure for the N-formylation of secondary amines using organosilicon chemistryThe Journal of Organic Chemistry, 1984
- New Developments in Cationic and Anionic Aldehyde PolymerizationPublished by Walter de Gruyter GmbH ,1976
- Reactions of group IV organometallic compounds IX addition and subsequent β-elimination reactions of trimethylsilyl- and stannylamines with chloralTetrahedron Letters, 1968
- A New Synthesis of PerfluoroaldehydesJournal of the American Chemical Society, 1954